Suzuki homo-coupling reaction based fluorescent sensors for monosaccharides

Long-Wavelength, Reaction-Based, Fluorescent Sensors

An air stable and efficient palladium catalyst for Suzuki-Miyaura cross coupling reaction at room temperature

The cross-coupling reaction between phenylboronic acid and various types of aryl halides (Suzuki reaction) was carried out using a catalytic amount of a new palladium catalyst (1-benzyl-3-(1-benzyl-1-methylpyrrolidin-1-ium-2-yl) pyridin-1-ium palladium chloride [DBNT][PdCl4]) in poly (ethylene glycol) (PEG-200) in the presence of KOH as the base. This new catalyst was synthesized and...

An air stable and efficient palladium catalyst for Suzuki-Miyaura cross coupling reaction at room temperature

The cross-coupling reaction between phenylboronic acid and various types of aryl halides (Suzuki reaction) was carried out using a catalytic amount of a new palladium catalyst (1-benzyl-3-(1-benzyl-1-methylpyrrolidin-1-ium-2-yl) pyridin-1-ium palladium chloride [DBNT][PdCl4]) in poly (ethylene glycol) (PEG-200) in the presence of KOH as the base. This new catalyst was synthesized and...

Two-photon fluorescent microporous bithiophene polymer via Suzuki cross-coupling.

A microporous bithiophene polymer (MBP) stable up to 460 °C was synthesized using bithiophene and biphenyl as building blocks through Suzuki cross-coupling. The as-obtained MBP product exhibits green fluorescence peaked at 530 nm, and most interestingly, a two-photon fluorescence was observable from MBP upon excitation by an 800 nm femtosecond laser.

Silyl-protected dioxaborinanes: application in the Suzuki cross-coupling reaction.

The synthesis of a range of novel silyl-protected dioxaborinanes as a column- and bench-stable boron reagent were found to be advantageous to achieving good yields in palladium-catalysed cross-coupling reactions under standard conditions.